ON THE FIRST ALKALINE-CADMIUM-VANADIUM OX IDE HALIDE - K4CDV5O15CL

Authors
MUNCHAU S MULLERBUSCHBAUM H
Citation
S. Munchau et H. Mullerbuschbaum, ON THE FIRST ALKALINE-CADMIUM-VANADIUM OX IDE HALIDE - K4CDV5O15CL, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 51(4), 1996, pp. 493-497
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
51
Issue
4
Year of publication
1996
Pages
493 - 497
Database
ISI
SICI code
0932-0776(1996)51:4<493:OTFAOI>2.0.ZU;2-M
Abstract
Single crystals of K4CdV5O15Cl have been prepared by crystallization f rom melts. The yellow crystals show tetragonal symmetry, space group C 1/4-P4, a = 9.097(1), c = 5.331(2) Angstrom, Z = 1. K4CdV5O15Cl belon gs to the K4CuV5O15Cl type. V(1) forms V2O7 double tetrahedra connecte d by square V(2)O-5 pyramids and CdO4Cl2 octahedra. The crystal struct ure is discussed with respect to the isotypic compound K4CuV5O15Cl con sidering a short V(2)-O distance indicative of a vanadinyl group.