METAL-COMPLEXES OF FUNCTIONALIZED SULFUR- CONTAINING LIGANDS .10. SYNTHESIS OF RUTHENIUM(II) AND PLATINUM(II) 1-ALKYNE-1-THIOLATO COMPLEXES- X-RAY STRUCTURE-ANALYSIS OF TRANS-(PH(3)P)(2)PT[S-C-C-C(CH3)(3)](2)

Authors
WEIGAND W WEISHAUPL M ROBL C
Citation
W. Weigand et al., METAL-COMPLEXES OF FUNCTIONALIZED SULFUR- CONTAINING LIGANDS .10. SYNTHESIS OF RUTHENIUM(II) AND PLATINUM(II) 1-ALKYNE-1-THIOLATO COMPLEXES- X-RAY STRUCTURE-ANALYSIS OF TRANS-(PH(3)P)(2)PT[S-C-C-C(CH3)(3)](2), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 51(4), 1996, pp. 501-505
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
51
Issue
4
Year of publication
1996
Pages
501 - 505
Database
ISI
SICI code
0932-0776(1996)51:4<501:MOFSCL>2.0.ZU;2-G
Abstract
The 1-alkyne-1-thiolates R-C=C-SLi [1a: R = C(CH3)(3); 1b: R = C6H11] react with L(2)PtCl(2) (L = PPh(3), 1/2 dppe) and CpRu(PPh(3))(2)Cl, r espectively to give the complexes trans-(Ph(3)P)(2)Pt[S-C=C-C(CH3)(3)] (2) (2a), cis-dppePt[S-C=C-C(CH3)(3)](2) (2b), and CpRu(PPh(3))(2)-(S- C=C-R) [3a: R = C(CH3)(3), 3b: R = C6H11]. 2a has been characterized b y P-31 CP/MAS NMR spectroscopy and its crystal structure determined by X-ray diffraction.