OPTICAL-ABSORPTION OF THE AURIDES M(3)AUO (M=K, RB, CS)

Citation
C. Feldmann et M. Jansen, OPTICAL-ABSORPTION OF THE AURIDES M(3)AUO (M=K, RB, CS), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 51(4), 1996, pp. 607-608
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
09320776
Volume
51
Issue
4
Year of publication
1996
Pages
607 - 608
Database
ISI
SICI code
0932-0776(1996)51:4<607:OOTAM(>2.0.ZU;2-T
Abstract
The optical absorption of the aurides M(3)AuO (M = K, Rb, Cs) and CsAu has been determinated by UV/VIS spectroscopy. The band gaps have been found to be 2,35(2) eV (Cs3AuO) and 2,30(2) eV (CsAu). This correspon ds to a more pronounced anionic character of gold in Cs3AuO as compare d to CsAu. In the case of K3AuO and Rb3AuO no band gap was detectable.