H. Hoshi et al., ANISOTROPIC 2ND-HARMONIC GENERATION OF ELECTRIC QUADRUPOLAR ORIGIN INCOPPER PHTHALOCYANINE FILMS EPITAXIALLY GROWN BY MOLECULAR-BEAM EPITAXY, Physical review. B, Condensed matter, 53(19), 1996, pp. 12663-12665
In order to investigate relatively strong second-harmonic generation (
SHG) in centrosymmetric molecular films of copper phthalocyanine (CuPc
), we have epitaxially grown CuPc films with D-4h symmetry by the mole
cular-beam epitaxy technique. SHG exhibits a periodic change while rot
ating the film about its C-4 axis. This fact indicates that electric q
uadrupole and/or electric quadrupole coupling mechanisms significantly
contribute to SHG.