We have studied the interband transitions from undoped and modulation-
doped Al0.25Ga0.75As/AlAs multiple-quantum-well structures (the latter
were doped n type in the Al0.25Ga0.75As layers). Two types of transit
ions have been observed: Type I associated with electron-hole recombin
ation in the Al0.25Ga0.75As layers and type II between electrons in th
e Xxy and Xz valleys of the AlAs layers and holes confined in the Al0.
25Ga0.75As layers. In undoped samples the luminescence associated with
type-II transitions is dominated by phonon replicas. In contrast, the
intensities of the zero-phonon X(xy)h(1) and X(z)h(1) transitions in
modulation-doped samples are comparable to those of the replicas. Unde
r optical pumping the type-II transitions in undoped samples show a pr
onounced blueshift due to band bending. Under high pumping intensity,
the spectra from the undoped samples strongly resemble those from the
modulation-doped structures.