Sh. Qian et al., CRITICAL-BEHAVIOR AT THE SMECTIC-A TO NEMATIC TRANSITION CONFINED TO A RANDOM NETWORK, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 53(5), 1996, pp. 4291-4294
The smectic-A to nematic (Sm-A-N) transition was studied confined to t
he randomly interconnected voids of Millipore filters via a high resol
ution calorimetry. The heat capacity peaks evolve from sharp and promi
nent to broad and small depending on void size. The random confinement
drives the heat capacity critical exponent from the bulk value toward
s zero, indicating a confinement-induced decoupling of smectic and nem
atic order parameters.