In this work, the near infrared to visible up-conversion process was s
tudied in Er3+ doped LiNbO3 single-crystal fibers. The absorption spec
tra of the I-4(9/2) multiplet and site-selective excitation of up-conv
erted emission from the S-4(3/2) multiplet were measured at 10 K. Mult
iple sites for Er3+ were found to exist in the fiber samples. They fal
l into two groups which may be related to the substitution of Li and N
b by Er. Near-infrared excitation spectra of the up-conversion and tra
nsient dynamics have shown that either excited state absorption (ESA)
or energy transfer up-conversion (ETU) processes play dominant roles a
t certain pump wavelengths. In addition, laser-heating-induced up-conv
ersion or photon avalanche up-conversion may also take place at some p
ump wavelengths.