In this paper, site occupations of Er3+ and Cr3+ in LiNbO3 (LNO) singl
e crystal fibers are discussed. A pairing structure of Er-Cr tends to
provide a geometric advantage for cooperative processes, Efficient up-
converted energy transfer from Er to Cr tvas observed by pumping the I
-4(9/2) state in the near infrared. Downward energy transfer from Cr3 to Er3+ was studied by pumping the T-4(2) State of Cr3+. The up-conve
rted and the downward energy transfer can be used to develop diode-pum
ped tunable lasers or to sensitize 1.5 mu m Er lasers, respectively.