Our chemical studies on Cycas circinalis seeds from Guam has provided
two new nonprotein amino acids, N-(3'-one-5'-methyl)-hexylalanine and
leucine betaine. N-methylisoleucine, previously reported as a componen
t of naturally occurring peptides, has been isolated as a free amino a
cid from the seeds of Phaseolus vulgaris (pinto bean), together with S
-methylcysteine, pipecolic acid and a dipeptide, gamma-glutamyl-leucin
e.