MANNICH-BASES AS MODEL COMPOUNDS FOR INTRAMOLECULAR HYDROGEN-BONDING .1. SOLID-STATE STRUCTURES AND MOLECULAR CALCULATIONS

Authors
KOLL A WOLSCHANN P
Citation
A. Koll et P. Wolschann, MANNICH-BASES AS MODEL COMPOUNDS FOR INTRAMOLECULAR HYDROGEN-BONDING .1. SOLID-STATE STRUCTURES AND MOLECULAR CALCULATIONS, Monatshefte fuer Chemie, 127(5), 1996, pp. 475-486
Citations number
45
Categorie Soggetti
Chemistry
Journal title
Monatshefte fuer Chemie → ACNP
ISSN journal
00269247
Volume
127
Issue
5
Year of publication
1996
Pages
475 - 486
Database
ISI
SICI code
0026-9247(1996)127:5<475:MAMCFI>2.0.ZU;2-1
Abstract
A survey of the structures and the properties of the hydrogen bonds in ortho-aminomethyl-phenols and -naphthols in the solid state is presen ted. The results are compared with molecular structure calculations. T he solid state complexes can exist in the molecular or in zwitterionic form. In the last case, only intermolecular hydrogen bonds forming cy clic dimers or linear chains were detected.