ASYMMETRIC BIOCHEMICAL REDUCTION, ACYLATION AND HYDROLYSIS IN THE (DIENE)FE(CO)3 SERIES - EXPERIMENTAL RESULTS AND MOLECULAR MODELING STUDIES

Authors
HOWELL JAS PALIN MG JAOUEN G TOP S ELHAFA H CENSE JM
Citation
Jas. Howell et al., ASYMMETRIC BIOCHEMICAL REDUCTION, ACYLATION AND HYDROLYSIS IN THE (DIENE)FE(CO)3 SERIES - EXPERIMENTAL RESULTS AND MOLECULAR MODELING STUDIES, Tetrahedron : asymmetry, 4(6), 1993, pp. 1241-1252
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
4
Issue
6
Year of publication
1993
Pages
1241 - 1252
Database
ISI
SICI code
0957-4166(1993)4:6<1241:ABRAAH>2.0.ZU;2-C
Abstract
Asymmetric reduction using bakers yeast and asymmetric acyl transfer u sing porcine pancreatic lipase may be used in the kinetic resolution a nd desymmetrization of acyclic (diene)Fe(CO)3 complexes bearing CHO an d CH2OH substituents respectively. The results may be interpreted in t erms of current active site models for these biotranformations.