VANTHOFFS EQUATION FOR ENDOREVERSIBLE CHEMICAL-REACTIONS

Authors
ANGULOBROWN F ARIASHERNANDEZ LA
Citation
F. Angulobrown et La. Ariashernandez, VANTHOFFS EQUATION FOR ENDOREVERSIBLE CHEMICAL-REACTIONS, Journal of physical chemistry, 100(21), 1996, pp. 9193-9195
Citations number
29
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
100
Issue
21
Year of publication
1996
Pages
9193 - 9195
Database
ISI
SICI code
0022-3654(1996)100:21<9193:VEFEC>2.0.ZU;2-I
Abstract
We propose that the so-called van't Hoff's equation for the enthalpy c hanges in a chemical reaction may be modified in the context of endore versible thermodynamics. This modification takes into account the role played by the heat supplied by the thermal bath for maintaining const ant the temperature of the chemical system. We analyze the reaction of hydrogen iodide synthesis by means of the modified van't Hoff's equat ion.