The esterification of various hydrophilic diols with fatty acids catal
yzed by Lipolase(TM) was carried out in water-in-oil (w/o) microemulsi
on systems stabilized with sodium(bis-2-ethylhexyl)sulphosuccinate (AO
T) as surfactant in isooctane. Mono- and di-esters were selectively sy
nthesized with high reaction rates. The product distribution depends o
n substrates concentration. Microemulsions appear to be an effective a
nd fast system for esterification of diols.