SYNTHESIS AND THERMAL TRANSITIONAL PROPERTIES OF SIDE-CHAIN LIQUID-CRYSTALLINE POLYACRYLATES CONTAINING PARA-NITROAZOBENZENE AS MESOGENIC GROUPS

The synthesis and characterization of side-chain liquid crystalline (L C) polyacrylates containing para-nitroazobenzene (Pn) as mesogenic gro ups were described. Homopolymers with 3 and 4 carbon atoms in the spac ers were non-LC polymers; for homopolymers with 6 carbon atoms in the spacer, nematic LC behavior was observed. Copolymers with acrylic acid as one component exhibited an S-Ad phase according to the WAXD result s which showed the d/l of 1.4-1.54 for the copolymers with 3, 4, and 6 carbon atoms in the spacers. Considering the molecular structure as w ell as the WAXD results of the copolymers, the possible molecular arra ngement in the smectic Sad phase was proposed, in which the smectic la yers were composed of the antiparallel mesogens and the antiparallel a rrangement was considered to be enhanced due to the H bond between - C OOH and - NO2. The stress-induced orientational phenomena of Pn in the LC states was also discussed. (C) 1996 John Wiley & Sons, Inc.