CAR PHASE REACTIONS IN SILENT ELECTRIC-DISCHARGES .3. INVESTIGATION OF CHEMICAL-REACTIONS INVOLVING ELECTRON-MOLECULE COLLISIONS IN VARIOUSMIXTURES OF O-2 WITH AR, N-2 OR CO

Citation
G. Siposnagy et al., CAR PHASE REACTIONS IN SILENT ELECTRIC-DISCHARGES .3. INVESTIGATION OF CHEMICAL-REACTIONS INVOLVING ELECTRON-MOLECULE COLLISIONS IN VARIOUSMIXTURES OF O-2 WITH AR, N-2 OR CO, Ozone: science & engineering, 18(2), 1996, pp. 159-171
Citations number
17
Categorie Soggetti
Environmental Sciences
ISSN journal
01919512
Volume
18
Issue
2
Year of publication
1996
Pages
159 - 171
Database
ISI
SICI code
0191-9512(1996)18:2<159:CPRISE>2.0.ZU;2-F
Abstract
Electron-molecule collisions play a significant role in chemical trans formations in a silent electric discharge. The reaction rate coefficie nts of electron-molecule collisions in various gaseous mixtures of Ar, N-2 or CO with O-2 have been investigated. These coefficients can be determined experimentally and calculated theoretically. The measured v alues are in good agreement with those calculated by theoretical metho ds. The reaction rate coefficients of electron-O-2, molecule collision s increase with decrease of the amount of O-2 in Ar/O-2 mixtures, but decrease with decrease of the amount of O-2 in N-2/O-2 or CO/O-2 mixtu res.