I. Heynderickx et Dj. Broer, THERMOOPTICAL PROPERTIES OF A POLYMER-DISPERSED LIQUID-CRYSTALLINE POLYMER, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 263, 1995, pp. 415-427
A side-chain liquid crystalline polymer dispersed into an amorphous po
lymer matrix can be used as a thermo-optical device that exhibits scat
tering at low temperatures and becomes transparent when heated above t
he clearing temperature of the Liquid crystalline polymer. The blend o
f the side-chain liquid crystalline polymer and the UV-polymerizable m
onomer is yet two-phasic before polymerization and exhibits some addit
ional phase separation during polymerization. Especially the thermal s
tability, but also the mechanical stability, of the thermo-optical dev
ice is considerably improved when dispersing a Liquid crystalline poly
mer instead of a low molar mass liquid crystal into a polymer matrix.