I. Mason et al., A SWITCHABLE LIQUID-CRYSTAL IMPREGNATED POROUS POLYMER DEVICE, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 263, 1995, pp. 567-575
This paper describes the fabrication and performance of a novel device
based on liquid crystals dispersed in a polymer matrix. A low molecul
ar weight Liquid crystal material is introduced into a pre-formed, thi
n, porous, low density polymer film. Application of an electric field
across the thin film produces a change in the transmission of the film
just as in conventional Polymer Dispersed Liquid Crystals (PDLC) due
to the reorientation of the liquid crystal director. Thus the device a
cts as a shutter. One significant advantage of this type of device ove
r conventional PDLC is that there is no intermixing of the liquid crys
tal and monomeric material. Also compressible porous polymer matrices
can be formed(1) giving the potential for controllably distorting the
pores in a given direction. The formation and switching characteristic
s of a device using a porous polymer based on styrene and divinylbenze
ne is described.