Y. Tomm et al., EFFECTS OF DOPING ON THE ELECTRONIC-PROPERTIES OF SEMICONDUCTING IRONDISILICIDE, Materials science & engineering. B, Solid-state materials for advanced technology, 37(1-3), 1996, pp. 215-218
Undoped and doped beta-FeSi2 single crystals were prepared by chemical
transport reaction using iodine as transporting agent. The doping ele
ments used were Co, Mn, Cr and Ni. The effect of impurities was studie
d by EPR and electrical measurements, The impurities substitute Fe on
its two inequivalent lattice sites. Electrical measurements indicated
p-type behavior. For Cr-doped samples an activation energy of 75 meV w
as determined. Optical studies on (Fe1-xCox)Si-2(x less than or equal
to 0.15) layers prepared by ion implantation into Si(100) showed a mon
otonous decrease of the gap.