KINETIC EVIDENCE FOR THE DEPENDENCE OF SURFACE-REACTION RATES ON THE DISTRIBUTION OF REACTANTS ON THE SURFACE

Authors
Citation
Md. Xu et al., KINETIC EVIDENCE FOR THE DEPENDENCE OF SURFACE-REACTION RATES ON THE DISTRIBUTION OF REACTANTS ON THE SURFACE, The Journal of chemical physics, 104(21), 1996, pp. 8825-8828
Citations number
24
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
104
Issue
21
Year of publication
1996
Pages
8825 - 8828
Database
ISI
SICI code
0021-9606(1996)104:21<8825:KEFTDO>2.0.ZU;2-#
Abstract
Two kinetically distinct types of oxygen atoms can be identified durin g the isothermal oxidation of CO on Pt(111) even though they all sit i n identical sites at the start of the reaction. This is explained by a lowering in the reaction activation barrier with oxygen islanding. (C ) 1996 American Institute of Physics.