Md. Xu et al., KINETIC EVIDENCE FOR THE DEPENDENCE OF SURFACE-REACTION RATES ON THE DISTRIBUTION OF REACTANTS ON THE SURFACE, The Journal of chemical physics, 104(21), 1996, pp. 8825-8828
Two kinetically distinct types of oxygen atoms can be identified durin
g the isothermal oxidation of CO on Pt(111) even though they all sit i
n identical sites at the start of the reaction. This is explained by a
lowering in the reaction activation barrier with oxygen islanding. (C
) 1996 American Institute of Physics.