SYNTHESIS AND CRYSTAL-STRUCTURE OF A POLYMERIC COMPLEX [S4CD17(SPH)(24)(CH3OCS2)(4 2)](N)CENTER-DOT-NCH(3)OH/

Authors
JIN XG TANG KL JIA SJ TANG YQ
Citation
Xg. Jin et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A POLYMERIC COMPLEX [S4CD17(SPH)(24)(CH3OCS2)(4 2)](N)CENTER-DOT-NCH(3)OH/, Polyhedron, 15(15), 1996, pp. 2617-2622
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
15
Year of publication
1996
Pages
2617 - 2622
Database
ISI
SICI code
0277-5387(1996)15:15<2617:SACOAP>2.0.ZU;2-M
Abstract
The three dimensional polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2) ](n) . nCH(3)OH (1) has been synthesized from the reaction of [Cd-4(SP h)(6)(SPh)(4/2)](n) with CS2, DMF and MeOH, and structurally character ized by X-ray diffraction analysis. Its repeat unit is a 17-nuclear ca dmium cluster which is linked to four surrounding aggregates through f our CH3OSC2- ligands. The method of synthesis is also discussed. Copyr ight (C) 1996 Elsevier Science Ltd.