The impedance responses and current-overpotential characteristics were
studied for oxygen reducing cathodes, stoichiometric La1-xSrxMnO3 (x
= 0.16-0.20) in solid oxide fuel cells, under varying conditions of te
mperature (700-900 degrees C) and oxygen partial pressure (1-10(-4) at
m) for two distinctly different electrode morphologies (porous and den
se structure). An electrode densified at the interface with the yttria
-stabilized zirconia solid electrolyte was more efficient in this stud
y. The reaction at the finely porous LSM proceeds via the triple phase
boundary and ineffectively uses the mixed conductivity property of th
e material. Reaction mechanisms for both cases (porous and dense struc
ture) are discussed and compared with the literature. A new, two-layer
ed cathode structure is proposed. Copyright (C) 1996 Elsevier Science
Ltd.