1,2-DI-TERT-BUTYLDIAZIRIDINE

Authors
KOSTYANOVSKY RG KORNEEV VA CHERVIN II VOZNESENSKY VN PUZANOV YV RADEMACHER P
Citation
Rg. Kostyanovsky et al., 1,2-DI-TERT-BUTYLDIAZIRIDINE, Mendeleev communications, (3), 1996, pp. 106-107
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
3
Year of publication
1996
Pages
106 - 107
Database
ISI
SICI code
0959-9436(1996):3<106:1>2.0.ZU;2-J
Abstract
1,2-Di-tert-butyldiaziridine 1 has been synthesized for the first time and its H-1 and C-13 NMR spectra studied in comparison with model dia ziridines 8-10. Its photoelectron and mass spectra have been measured and its structure optimized by semiempirical and ab initio calculation s; considerable steric deformation of the CH2 ring fragment and mutual approach of tert-butyl groups is shown.