REACTIONS OF ACYL ISOTHIOCYANATES WITH DIPHENYLDIAZOMETHANE

Authors
LABBE G FRANCIS A DEHAEN W BOSMAN J
Citation
G. Labbe et al., REACTIONS OF ACYL ISOTHIOCYANATES WITH DIPHENYLDIAZOMETHANE, Bulletin des Societes chimiques belges, 105(5), 1996, pp. 253-258
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
105
Issue
5
Year of publication
1996
Pages
253 - 258
Database
ISI
SICI code
0037-9646(1996)105:5<253:ROAIWD>2.0.ZU;2-P
Abstract
The title reactions yield labile 4,5-dihydro-1,3-oxazole-4-spiro-2'-th iiranes 4 which isomerize in solution to the thietan-3-imines 5. This isomerization also occurs when the spiro compounds are heated to their melting points, but here the desulfurized products 8 and 9 are also f ormed in some cases. These are also the products obtained by SO2 extru sion of the sulfones 10 derived from 5.