SYNTHESIS, CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF NEW QUATERNARY SULFIDES WITH THE BACU2S2-TYPE

Authors
MOUALLEMBAHOUT M POTEL M HALET JF PADIOU J CAREL C RETATSAVELEVA MR
Citation
M. Mouallembahout et al., SYNTHESIS, CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF NEW QUATERNARY SULFIDES WITH THE BACU2S2-TYPE, European journal of solid state and inorganic chemistry, 33(5), 1996, pp. 483-493
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
33
Issue
5
Year of publication
1996
Pages
483 - 493
Database
ISI
SICI code
0992-4361(1996)33:5<483:SCAPON>2.0.ZU;2-E
Abstract
New significant examples of layered metal chalcogenide materials with the tetragonal ThCr2Si2 type structure (S.G. 14/mmm), Ba(1-x)M(x)Cu(2) S(2) (M = K, x = 0.20; M = Rb, x = 0.15) and MCuMnS(2) (M = K, Rb) hav e been synthetized and characterized. In contrast to the stoichiometri c semiconducting parent compound BaCu2S2, these new compounds exhibit metallic properties which are explained in terms of band structure. A new isostructural compound Rb2Cu3FeS4 is also mentioned.