NEW CHEMISTRY OF CYCLIC, S-TRANS-ENAMINONES - ADDITION OF GRIGNARD-REAGENTS TO ENAMINONES DERIVED FROM 2-METHYLCYCLOHEXANE-1,3-DIONE

Authors
SHAWE TT LANDINO LM ROSS AA PROKOPOWICZ AS ROBINSON PM CANNON A
Citation
Tt. Shawe et al., NEW CHEMISTRY OF CYCLIC, S-TRANS-ENAMINONES - ADDITION OF GRIGNARD-REAGENTS TO ENAMINONES DERIVED FROM 2-METHYLCYCLOHEXANE-1,3-DIONE, Tetrahedron letters, 37(22), 1996, pp. 3823-3824
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
22
Year of publication
1996
Pages
3823 - 3824
Database
ISI
SICI code
0040-4039(1996)37:22<3823:NCOCS->2.0.ZU;2-2
Abstract
Grignard reagents add to cyclic s-trans enaminones to give the cycloal kenone after aqueous hydrolysis. In some cases a competitive double ad dition takes place. These reactions have been found to be solvent- and reagent-selective. Copyright (C) 1996 Elsevier Science Ltd