A. Ziehfreund et al., OXYGEN-ION CONDUCTIVITY OF PLANTIUM-IMPREGNATED STABILIZED ZIRCONIA IN BULK AND MICROPOROUS MATERIALS, Advanced materials, 8(5), 1996, pp. 424
The effect of platinum impregnation on the ionic conductivity of yttri
a stabilized zirconia (YSZ) has been determined using complex impedanc
e measurements in the frequency range 10(1)-10(7) Hz. Ionic conductivi
ties and the corresponding activation enthalpies are reported for the
temperature range 200-600 degrees C. Platinum agglomerated at the grai
n boundaries of polycrystalline samples reduces ion transport across t
he intergranular zone. The evaporation Impregnated Stabilized Zirconia
in Bulk and recondensation of YSZ and the addition of Pt results in p
orous materials and Microporous Materials with improved oxygen ion con
ductivity.