KINETIC REGULARITIES OF CONVERSION OF OZONE COMPLEXES WITH ARENES

Authors
AVZYANOVA EV KABALNOVA NN SHERESHOVETS VV
Citation
Ev. Avzyanova et al., KINETIC REGULARITIES OF CONVERSION OF OZONE COMPLEXES WITH ARENES, Russian chemical bulletin, 45(2), 1996, pp. 356-359
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
2
Year of publication
1996
Pages
356 - 359
Database
ISI
SICI code
1066-5285(1996)45:2<356:KROCOO>2.0.ZU;2-9
Abstract
The kinetic regularities of conversion of ozone complexes with several substituted benzenes (ArX = C(6)H(5)Me, C(6)H(5)Et, C(6)H(5)CHMe(2), C(6)H(5)CMe(3), C6H5F, C6H5Cl, m-BrC(6)H(5)Me, and C6H5CH2Cl) were stu died by spectrophotometry. The rate of consumption of ArX . O-3 in a C H2Cl2-ArX solution obeys the kinetic equation W = k(0)[ArX . O-3]+k(1) [ArX . O-3][ArX]. The values of the rate constants k(0) and k(1) for t he complexes studied were determined at -60 divided by 0 degrees C.