FRAGMENTATION OF -2-(5H-DIBENZO[A,D]CYCLOHEPTEN-5-YL)-1-PHENYLETHYL CATION IN SUPERACID

Authors
OSADCHII SA STANESCU MD MAMATYUK VI SHUBIN VG
Citation
Sa. Osadchii et al., FRAGMENTATION OF -2-(5H-DIBENZO[A,D]CYCLOHEPTEN-5-YL)-1-PHENYLETHYL CATION IN SUPERACID, Russian chemical bulletin, 45(2), 1996, pp. 381-383
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
2
Year of publication
1996
Pages
381 - 383
Database
ISI
SICI code
1066-5285(1996)45:2<381:FO-C>2.0.ZU;2-T
Abstract
The -2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation generate d under ''long life'' conditions undergoes fragmentation to afford 5H- dibenzo[a,d]cycloheptenyl- and methylphenylhydroxycarbinyl cations but does not undergo carbocationic cyclization.