REACTION OF 2,6-DIBENZYLIDENECYCLOHEXANONE WITH PHOSPHORUS-PENTACHLORIDE - TRIPLE FUNCTIONALIZATION OF THE ISOSEMIQUINOID SYSTEM

Authors
NIKANOROV VA ROGACHEV AD GALAKHOV MV SHCHERBINA TM ZAGOREVSKII DV ROZENBERG VI REUTOV OA KAVERIN VV YUREV VP
Citation
Va. Nikanorov et al., REACTION OF 2,6-DIBENZYLIDENECYCLOHEXANONE WITH PHOSPHORUS-PENTACHLORIDE - TRIPLE FUNCTIONALIZATION OF THE ISOSEMIQUINOID SYSTEM, Russian chemical bulletin, 45(2), 1996, pp. 424-426
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
2
Year of publication
1996
Pages
424 - 426
Database
ISI
SICI code
1066-5285(1996)45:2<424:RO2WP>2.0.ZU;2-J
Abstract
The reaction of 2,6-dibenzylidenecyclohexanone with PCl5 occurs via th e sequential stages of desoxychlorination and substitutional phosphory lation to form (after oxidation, methoxylation, and hydrolysis on the surface of the chromatographic SiO2 adsorbent) organophosphorus produc ts of the 1-(alpha-chloro-, alpha-hydroxy-, or pha-(dimethylphosphoryl )benzylidene)cyclohex-1-ene series.