ELECTROSPRAY MASS-SPECTROMETRIC STUDY OF HOMOGENEOUS CATALYTIC-SYSTEMPD(CF3COO)(2)-PH(2)P(CH2)(3)PPH(2)-MEOH ME(2)CO-H-2 FOR COPOLYMERIZATION OF ETHYLENE AND CARBON-MONOXIDE/

Authors
DZHABIEVA ZM KOZLOVSKII VP SHULGA YM DODONOV AF BELOV GP
Citation
Zm. Dzhabieva et al., ELECTROSPRAY MASS-SPECTROMETRIC STUDY OF HOMOGENEOUS CATALYTIC-SYSTEMPD(CF3COO)(2)-PH(2)P(CH2)(3)PPH(2)-MEOH ME(2)CO-H-2 FOR COPOLYMERIZATION OF ETHYLENE AND CARBON-MONOXIDE/, Russian chemical bulletin, 45(2), 1996, pp. 474-476
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
2
Year of publication
1996
Pages
474 - 476
Database
ISI
SICI code
1066-5285(1996)45:2<474:EMSOHC>2.0.ZU;2-S
Abstract
The catalytic system Pd(CF3COO)(2)-Ph(2)P(CH2)(3)PPh(2)-MeOH/Me(2)CO w as studied by electrospray mass spectrometry. The {[Pd(dppp)(2)](2+), [(dppp)(2)Pd(CF3COO)](+), [(dppp)Pd(CF3COO)](+), and [(dppp)Pd(CF3COO) (2)Pd(dppp)](2+)} cations were found in the system. The addition of H2 O to the system resulted in the formation of binuclear bicharged ions [(dppp)Pd(OH)](2+)(2) and their associates with water.