SYNTHESIS, CHARACTERIZATION, AND MOLECULAR-STRUCTURE OF THE FIRST CLOSO-HYDRIDO COMPLEXES OF OSMIUM WITH CARBORANE LIGANDS - CLOSO-3,3-(PPH(3))(2)-3-H-3-CL-3,1,2-OSC2B9H11 AND O-3,3-(PPH(3))(2)-3,3-H-2-1,2-ME(2)-3,1,2-OSC2B9H9

Authors
CHIZHEVSKY IT PETROVSKII PV SOROKIN PV BREGADZE VI DOLGUSHIN FM YANOVSKY AI STRUCHKOV YT DEMONCEAU A NOELS AF
Citation
It. Chizhevsky et al., SYNTHESIS, CHARACTERIZATION, AND MOLECULAR-STRUCTURE OF THE FIRST CLOSO-HYDRIDO COMPLEXES OF OSMIUM WITH CARBORANE LIGANDS - CLOSO-3,3-(PPH(3))(2)-3-H-3-CL-3,1,2-OSC2B9H11 AND O-3,3-(PPH(3))(2)-3,3-H-2-1,2-ME(2)-3,1,2-OSC2B9H9, Organometallics, 15(11), 1996, pp. 2619-2623
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
11
Year of publication
1996
Pages
2619 - 2623
Database
ISI
SICI code
0276-7333(1996)15:11<2619:SCAMOT>2.0.ZU;2-O
Abstract
Novel 12-vertex closo-hydridometallacarboranes 3,1,2-[(PPh(3))(2)OsHXC (2)B(9)H(11)] (la,b: X = Cl, H) and 3,1,2-[(PPh(3))(2)OsH2-1,2-Me(2)C( 2)B(9)H(9)] (Ic) have been synthesized via oxidative addition of K+ sa lts of the Izido-carborane anions [nido-7,8-R(2)-7,8-C2B9H10](-) (R = H, Me), respectively, to OsCl2(PPh(3))(3) and characterized by spectro scopic (NMR and IR) as well as by single-crystal X-ray diffraction stu dies of 1a,c.