A FACILE SYNTHESIS OF 4,4-BIS(TRIFLUOROMETHYL)IMIDAZOLINES VIA A NOVEL OXIDATIVE IMIDAZOLE REARRANGEMENT

Authors
LI HY DELUCCA I DRUMMOND S BOSWELL GA
Citation
Hy. Li et al., A FACILE SYNTHESIS OF 4,4-BIS(TRIFLUOROMETHYL)IMIDAZOLINES VIA A NOVEL OXIDATIVE IMIDAZOLE REARRANGEMENT, Heterocycles, 43(5), 1996, pp. 937-940
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
43
Issue
5
Year of publication
1996
Pages
937 - 940
Database
ISI
SICI code
0385-5414(1996)43:5<937:AFSO4V>2.0.ZU;2-P
Abstract
Oxidation of imidazole (1) with singlet oxygen or m-chloroperbenzoic a cid affords novel 4,4-bis(trifluoromethyl)imidazolines in high yield v ia a unique oxidative ring opening and subsequent acid catalyzed dehyd rocyclization.