A nem supported catalyst system Mas proposed to produce N-phenylmaleim
ide (PMI) from N-phenylmaleamic acid (PMA) in an improved yield. Follo
wings are important factors to affect the yield of PMI according io co
nsideration of the details of dehydration process of PMA. 1) interfaci
al area between the organic solvent phase and the catalyst phase. 2) T
hickness of the catalyst phase. 3) Agitation. The supported catalyst i
mproved considerably the yield of PMI under optimum conditons or I) an
d 2). It Nas proved that a suppress of the hydrolysis of PMA in former
half of the reaction brought about the high yield.