MODELING OF PROCESSES OF HYDROPEROXIDE EPOXIDATION OF OLEFINS - INFLUENCE OF AN OLEFIN ON THE ACTIVITY OF THE DECOMPOSITION CATALYST FOR ETHYLBENZENE HYDROPEROXIDE

Authors
AKHMEDYANOVA RA MONAYENKOV AY LITVINTSEV IY SAPUNOV VN
Citation
Ra. Akhmedyanova et al., MODELING OF PROCESSES OF HYDROPEROXIDE EPOXIDATION OF OLEFINS - INFLUENCE OF AN OLEFIN ON THE ACTIVITY OF THE DECOMPOSITION CATALYST FOR ETHYLBENZENE HYDROPEROXIDE, Petroleum chemistry, 36(1), 1996, pp. 78-82
Citations number
6
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
36
Issue
1
Year of publication
1996
Pages
78 - 82
Database
ISI
SICI code
0965-5441(1996)36:1<78:MOPOHE>2.0.ZU;2-T
Abstract
An investigation has been made of the influence of additions of an ole fin (Ol) (nonene, cyclohexene) on the kinetics of consumption of ethyl benzene hydroperoxide (EBHP) in the presence of a complex molybdenum-c ontaining catalyst (CMC). It has been shown that, despite the change i n the activity of the catalyst in the decomposition reaction under the influence of the epoxidation products, the three routes of EBHP consu mption that were found earlier are maintained. The presence of monomer ic and oligomeric forms of the catalyst must also be taken into accoun t in the modelling of epoxidation. (C) 1996 Elsevier Science Ltd. All rights reserved.