THE WEAKEST BOND - COLLISIONS OF HELIUM DIMERS WITH XENON ATOMS

Citation
E. Buonomo et al., THE WEAKEST BOND - COLLISIONS OF HELIUM DIMERS WITH XENON ATOMS, Journal of physical chemistry, 100(22), 1996, pp. 9206-9215
Citations number
39
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
100
Issue
22
Year of publication
1996
Pages
9206 - 9215
Database
ISI
SICI code
0022-3654(1996)100:22<9206:TWB-CO>2.0.ZU;2-9
Abstract
The existence of an He-2 bound start is employed in an analysis of the possible outcomes from the low-energy collisions between helium dimer s and xenon atoms that are currently being observed in molecular beam experiments. Existing interaction potentials between helium atoms and between He and Xe atoms ape used to construct the necessary potential energy surface (PE). Various dynamical approximations for the evaluati on of elastic and total cross sections are reviewed, and the results a re analyzed in detail, helping us to clarify the specific physical mea nings of the various decoupling schemes used in the calculations. The special nature of this unusual diatomic target turns out to play, as e xpected, a crucial role in the cross section behavior at low collision energies.