Mv. Portnyagin et al., GEOCHEMICAL VARIABILITY OF BONINITE MAGMAS - EVIDENCE FROM MAGMATIC INCLUSIONS IN HIGHLY MAGNESIAN OLIVINE FROM LAVAS OF SOUTHWESTERN CYPRUS, PETROLOGY, 4(3), 1996, pp. 231-246
Detailed geochemical, mineralogical, and experimental studies of an Ol
-phyric boninite from the Mavrokolimbos area, southwestern Cyprus are
presented. Olivine phenocrysts have a primitive composition (Fo(87-92)
). They contain crystalline inclusions of magnesian orthopyroxene (Mg#
= 0.90-0.92), chromian spinel of variable composition [Cr/(Cr + Al) =
0.79-0.60], and syngenetic melt and fluid inclusions. The melt inclus
ions, which were quenched experimentally, were analyzed for major elem
ents (using electron microprobe), trace elements, and H2O (by ion micr
oprobe). The detected compositional variations of the melt inclusions
suggest a wide chemical diversity of the primary boninitic magmas and
the involvement of at least four independent components in their compo
sition. According to the proposed model, the boninite melts formed by
partial mantle melting in an open system, at an effective restite perm
eability of approximately 2%, a fact evident from the occurrence of an
ultradepleted melt [(Ce/Yb)(n) = 0.07]. The incipient mantle melting
began under the effect of the aqueous component. The primary fluid was
characterized by a low content of the most incompatible elements (H2O
/K2O > 150). Its origin was related to the dehydration of a subducted
slab. The enrichment of the boninite in LREE and LILE was due to the p
resence of an independent component [(La/Sm)(n) > 2, (K/La)(n) approxi
mate to 5, (K/Sr)(n) approximate to 5, (Sr/Ce)(n) approximate to 1], w
hich could be introduced in the mantle source by the aqueous component
percolating through the heterogeneously metasomatized mantle. Alterna
tively, the enriched component may have The genesis of this component
is related to potassic mantle metasomatism. The boninitic magmas inter
acted with silicic rocks/melts during the crystallization and produced
hybrid melts with anomalously high contents of HREE [Yb > 2.5 ppm,(Dy
/Ti)(n) > 5],Y, and Na, and low CaO/Al2O3 ratios (<0.75).