Vb. Naumov et al., FLUID OVERPRESSURE IN ANDESITE MELTS FROM CENTRAL SLOVAKIA - EVIDENCEFROM INCLUSIONS IN MINERALS, PETROLOGY, 4(3), 1996, pp. 265-276
Unusual melt inclusions, containing a very dense hydrous solution in a
ddition to glass, were found in plagioclase phenocrysts (An 68-36) of
andesite from the Stiavnica caldera in Central Slovakia. The fluid com
ponent of the inclusions is homogeneous or contains a gas phase. Accor
ding to measurements in 65 inclusions, ice melting temperatures vary f
rom -0.6 to -7.8 degrees C, which corresponds to a salinity of 0.9-11.
5 wt % equiv NaCl with an average value of 4.5 wt %. At T = 20 degrees
C, the solution of this salinity has a density of 1.00-1.08 g/cm(3) w
ith an average of 1.03 g/cm(3). The solution from melt inclusions with
a two-phase fluid component homogenizes into a liquid phase at 140-28
5 degrees C, which gives 0.79-0.97 g/cm(3) for the density of the hydr
ous fluid. The chemical composition of glass from the melt inclusions
is characterized, according to 15 electron microprobe analyses, by hig
h concentrations of SiO2 (72.6 wt %), K2O (6.4 wt %), and Cl (0.28 wt
%), and low contents of TiO2, MgO, and CaO. The calculation of water c
oncentration in the magma, including water in melt inclusions, yielded
high values of 7.1 to 13.3 wt %. The fluid pressure was very high dur
ing ma,oma crystallization-5.6 to 15-17 kbar at T = 800-900 degrees C.
At the same time, the CO2 fluid inclusions found in the cores of the
phenocrysts have a relatively low density (0.35 g/cm(3)), which corres
ponds to a fluid pressure of not more than 0.9-1.1 kbar at 800-1000 de
grees C. This value may be indicative of a magma chamber at a depth of
3-4 km. The occurrence of two different fluids in the same phenocryst
s-early CO2 at 0.9-1.1 kbar and late H2O at 5.6-17 kbar-indicates that
water was injected into a closed magma reservoir. Apparently, the sup
er-high fluid pressure was the factor responsible for magma rise towar
ds the earth's surface.