Io, innermost of Jupiter's large moons, is one of the most unusual obj
ects in the Solar System. Tidal heating of the interior produces a glo
bal heat flux 40 times the terrestrial value, producing intense volcan
ic activity and a global resurfacing rate averaging perhaps 1 cm yr(-1
). The volcanoes may erupt mostly silicate lavas, but the uppermost su
rface is dominated by sulfur compounds including SO2 frost. The volcan
oes and frost support a thin, patchy SO2 atmosphere with peak pressure
near 10(-8) bars. Self-sustaining bombardment of the surface and atmo
sphere by Io-derived plasma trapped in Jupiter's magnetosphere causes
escape of material from Io (predominantly sulfur, oxygen, and sodium a
toms, ions, and molecules) at a rate of about 10(3) kg s(-1). The resu
lting Jupiter-encircling torus of ionized sulfur and oxygen dominates
the Jovian magnetosphere and, together with an extended cloud of neutr
al sodium, is readily observable from Earth.