DO METAL PERCHLORATES ACT AS A CONVENTIONAL LEWIS-ACID IN THE ALLYLSTANNATION OF ALDEHYDES

Authors
NISHIGAICHI Y NAKANO N TAKUWA A
Citation
Y. Nishigaichi et al., DO METAL PERCHLORATES ACT AS A CONVENTIONAL LEWIS-ACID IN THE ALLYLSTANNATION OF ALDEHYDES, Journal of the Chemical Society. Perkin transactions. I, (11), 1993, pp. 1203-1204
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
11
Year of publication
1993
Pages
1203 - 1204
Database
ISI
SICI code
0300-922X(1993):11<1203:DMPAAA>2.0.ZU;2-D
Abstract
Lithium, magnesium and calcium perchlorates are found to promote the a ddition of allylic tin compounds to aldehydes via a six-membered cycli c transition state, although not acting as a conventional Lewis acid l ike BF3.