T. Hofman et C. Casanova, ON THE PHYSICAL CONTRIBUTION TO THE EXTEND REAL ASSOCIATED SOLUTION MODEL, Berichte der Bunsengesellschaft fur Physikalische Chemie, 100(4), 1996, pp. 490-495
Citations number
11
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
The mixing rules and the expressions of the physical contributions to
the excess functions of mixing given by the ERAS model are critically
re-examined, As a result, new and more rigorous equations are derived.
Calculations performed on the typical systems confirm meaningful diff
erences between the old and new formulation at low concentrations of t
he associated substance.