CHELATES OF PRASEODYMIUM(III), NEODYMIUM(III), SAMARIUM(III), GADOLINIUM(III), HOLMIUM(III), ERBIUM(III), THULIUM(III) AND YTTERBIUM(III) AND SOME SYMMETRICAL 1,5-DIPHENYL-3-CYANOFORMAZANS
Na. Darwish et al., CHELATES OF PRASEODYMIUM(III), NEODYMIUM(III), SAMARIUM(III), GADOLINIUM(III), HOLMIUM(III), ERBIUM(III), THULIUM(III) AND YTTERBIUM(III) AND SOME SYMMETRICAL 1,5-DIPHENYL-3-CYANOFORMAZANS, Journal of the Indian Chemical Society, 73(2-3), 1996, pp. 103-108
Potentiometric, conductimetric, ir, TG, molar conductance and magnetic
susceptibility studies have been carried out on the complexes of triv
alent Pr, Nd, Sm, Gd, Ho, Er, Tm and Yb with some symmetric 1,5-diphen
yl-3-cyanoformazans. The ionisation constants of the ligands and the f
ormation constants of their metal chelates have been determined potent
iometrically in solution. Complexation has also been studied by a cond
uctimetric titration method.