SYNTHESIS AND STRUCTURE OF THE 1ST PHOSPHINE OXIDE COMPLEX OF COPPER(I) - EVIDENCE FOR A MARKED BORDERLINE CHARACTER OF THE METAL CENTER

Authors
PILLONI G CORAIN B DEGANO M LONGATO B ZANOTTI G
Citation
G. Pilloni et al., SYNTHESIS AND STRUCTURE OF THE 1ST PHOSPHINE OXIDE COMPLEX OF COPPER(I) - EVIDENCE FOR A MARKED BORDERLINE CHARACTER OF THE METAL CENTER, Journal of the Chemical Society. Dalton transactions, (11), 1993, pp. 1777-1778
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
11
Year of publication
1993
Pages
1777 - 1778
Database
ISI
SICI code
0300-9246(1993):11<1777:SASOT1>2.0.ZU;2-P
Abstract
The remarkable stability of [Cu(dppf)(odppf)]BF4 [dppf = 1,1'-bis(diph enylphosphino)ferrocene, odppf = 1,1'-bis(oxodiphenylphosphoranyl)ferr ocene], characterized in the solid state by X-ray analysis and in solu tion by P-31 NMR spectroscopy, reveals a marked borderline character o f copper(I).