Ra. Vilaplana et F. Gonzalezvilchez, REACTION OF COPPER(II) WITH A METALLOPORPHYRIN - A TYPE OF SUPRAMOLECULAR-DRIVEN PORPHYRIN METALATION, Journal of the Chemical Society. Dalton transactions, (11), 1993, pp. 1779-1781
The reaction of the transfer of copper(II) from a chelating environmen
t to a porphyrin core, accelerated by cadmium(II) previously inserted
into the porphyrin, shows an unusual kinetic profile which is interpre
ted as being the result of supramolecular assembly formation.