REACTION OF COPPER(II) WITH A METALLOPORPHYRIN - A TYPE OF SUPRAMOLECULAR-DRIVEN PORPHYRIN METALATION

Citation
Ra. Vilaplana et F. Gonzalezvilchez, REACTION OF COPPER(II) WITH A METALLOPORPHYRIN - A TYPE OF SUPRAMOLECULAR-DRIVEN PORPHYRIN METALATION, Journal of the Chemical Society. Dalton transactions, (11), 1993, pp. 1779-1781
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03009246
Issue
11
Year of publication
1993
Pages
1779 - 1781
Database
ISI
SICI code
0300-9246(1993):11<1779:ROCWAM>2.0.ZU;2-4
Abstract
The reaction of the transfer of copper(II) from a chelating environmen t to a porphyrin core, accelerated by cadmium(II) previously inserted into the porphyrin, shows an unusual kinetic profile which is interpre ted as being the result of supramolecular assembly formation.