The ordering process in the hydrogen subsystem of the interstitial all
oy TbD2+x is described with the mean-field approximation to static-con
centration wave theory and with the results of neutron-diffraction exp
eriments. It is shown that the measured temperature dependence of the
intensity for the superstructure reflections in the alloy with composi
tion TbD2.18 is well represented by the calculated temperature depende
nce of the square of the order parameter. Furthermore, the computed tr
ansition temperatures for alloys with different concentrations x in th
e range 0 less-than-or-equal-to x less-than-or-equal-to 0. 25 are clos
e to those determined from resistivity and neutron-scattering experime
nts.