THEORETICAL INSIGHTS ON THE MECHANISM OF ALKENE EPOXIDATION BY H2O2 WITH TITANIUM SILICALITE

Authors
NEUROCK M MANZER LE
Citation
M. Neurock et Le. Manzer, THEORETICAL INSIGHTS ON THE MECHANISM OF ALKENE EPOXIDATION BY H2O2 WITH TITANIUM SILICALITE, Chemical communications, (10), 1996, pp. 1133-1134
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
10
Year of publication
1996
Pages
1133 - 1134
Database
ISI
SICI code
1359-7345(1996):10<1133:TIOTMO>2.0.ZU;2-R
Abstract
Ethlene preferentially attacks the oxygen closest to the titanium in H OO-Ti(OSiH3)(3)(MeOH) and HOO-TiL(3) (MeOH) cluster models of the acti ve Ti-site in TS1 due to a substantially reduced electrostatic repulsi on.