AN INTERSTITIAL PYROCHLORE FORMED BY CHEMICAL INTERCALATION OF OXYGEN

Authors
THOMSON JB ARMSTRONG AR BRUCE PG
Citation
Jb. Thomson et al., AN INTERSTITIAL PYROCHLORE FORMED BY CHEMICAL INTERCALATION OF OXYGEN, Chemical communications, (10), 1996, pp. 1165-1166
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
10
Year of publication
1996
Pages
1165 - 1166
Database
ISI
SICI code
1359-7345(1996):10<1165:AIPFBC>2.0.ZU;2-C
Abstract
Oxygen is intercalated, using a solution-based route at ambient temper ature, into a pyrochlore oxide, thus establishing a new class of pyroc hlore-based interstitial solid solutions: the specific system studied is Ce2Zr2O7 and compositions in the range Ce2Zr2O7+x, 0 < x < 0.36 are obtained; the structure of the most oxygen rich composition has been elucidated by powder neutron diffraction.