The adhesion force between modified AFM tips and a mica substrate has
been studied using an atomic force microscope. The force-distance curv
es measured by the microscope show that the adhesion force is sensitiv
e to the surface energies of the materials coated on the tips. The adh
esion force between a gold-coated tip and a mica surface is much large
r than that between a paraffin-coated tip and a mica surface. A simple
calculation shows that this behavior of the adhesion forces can be ac
counted for by the van der Waals and capillary forces between the AFM
tips and the substrate.