Several long chain esters of meso-tetrakis(para-carboxyphenyl)porphyri
n, and two of their metal complexes (Cu, Zn) have been prepared and ch
aracterized. Each of them exhibits at least one thermotropic phase tra
nsition below the clearing point to the isotropic liquid, but no defin
itive evidence of liquid crystallinity has been found by differential
scanning calorimetry, optical microscopy, or X-ray diffraction.