PREDICTION OF A PURE-CARBON PLANAR COVALENT METAL

Carbon is well-known as an insulator, a semimetal, a molecular solid, and a one-dimensional semiconductor or low-density-of-states metal. We propose a pure-carbon planar structure composed of pentagons and hept agons that is metallic with a density of states at the Fermi level of similar to 0.1 state per eV per atom. This structure, planar carbon pe ntaheptite, is metastable with a total energy per carbon atom comparab le to that of C-60. The structure can be rolled into tubes in a manner similar to graphite. Possible synthetic pathways are discussed.