We report a photoluminescence (PL) study from p-type gallium-doped SiC
epilayers, which reveals a PL spectrum constituted of a set of sharp
lines and interpreted as excitons bound to the Ga acceptor. The PL spe
ctrum consists of several zero-phonon lines, which are very close to o
r superimposed on the nitrogen-bound excitons in the 4H- and 6H-SiC. T
he intensity of the PL spectrum depends on the Ga concentration introd
uced during the growth of the epilayers. The applicability of the Hayn
es rule is shown for the accepters in SiC. A comparison with the alumi
num-bound exciton is also presented.